Why water?

So why not HF and NH3? Those two compounds have many (but not all) of the same properties that water does.

But, among other things, they are not stable at Earth's temperatures.

Water has an interesting phase diagram:

http://www.eso.org/seaspace/water/water2.html

This says that the liquid state of water is, surprisingly, more compact than the solid state (because if you push on water hard enough, you transition from solid to liquid at a constant temperature). This is another way of saying the solid water is less dense than liquid water: ice floats.

Also: at sufficiently low pressures, no liquid water can exist. Where does Mars fall on this plot?

However, it might be a case in which the best fit on the early Earth was water, but that under other conditions, other compounds are more suitable than water. For example: Titan's methane cycle, which we will talk about next week.

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